Ceramic matrix composites for corrosion-resistant next-generation nuclear reactor systems: A conceptual review of enhancements in durability against molten salt attack

Thompson Odion Igunma 1, *, Adeoye Taofik Aderamo 2 and Henry Chukwuemeka, Olisakwe 3

1 Independent Researcher, Florida, USA.
2 Independent Researcher, Lagos Nigeria.
3 Department of Mechanical Engineering, Nnamdi Azikiwe University, Awka Nigeria.
 
Review
Open Access Research Journal of Engineering and Technology, 2024, 07(02), 001–015.
Article DOI: 10.53022/oarjet.2024.7.2.0055
Publication history: 
Received on 28 August 2024; revised on 05 October 2024; accepted on 08 October 2024
 
Abstract: 
Ceramic matrix composites (CMCs) are emerging as a key material class for enhancing corrosion resistance in next-generation nuclear reactor systems, particularly in high-temperature molten salt environments. These environments, critical for advanced nuclear reactors such as molten salt reactors (MSRs), present severe challenges, including aggressive chemical attacks that degrade traditional structural materials over time. This conceptual review explores the development and application of CMCs to improve the durability and corrosion resistance of nuclear reactors exposed to molten salt attacks. CMCs, which consist of ceramic fibers embedded in a ceramic matrix, offer significant advantages, such as high thermal stability, mechanical strength, and improved corrosion resistance compared to conventional materials. This review examines how CMCs can be tailored to withstand harsh operational conditions, with a focus on the selection of ceramic phases, fiber-matrix interactions, and innovative fabrication techniques that enhance their protective capabilities. Key challenges addressed include the optimization of composite design to resist molten salt corrosion, the effects of temperature on the material properties, and the long-term stability of CMCs under extreme conditions. Advances in surface treatments, coatings, and the development of hybrid CMC systems are also discussed, highlighting their potential to further enhance durability. The review outlines the use of advanced characterization techniques, such as high-temperature corrosion testing and in situ microscopy, to evaluate CMC performance in molten salt environments. Additionally, it identifies knowledge gaps in current research, emphasizing the need for long-term studies on CMC behavior under realistic reactor conditions. This review concludes by proposing future research directions and technological advancements required to integrate CMCs into next-generation nuclear reactor designs, aiming to improve system reliability and operational safety.
 
Keywords: 
Ceramic Matrix Composites (CMCS); Corrosion Resistance; Molten Salt Environments; Nuclear Reactor Systems; Next-Generation Reactors; High-Temperature Stability; Composite Design; Durability; Surface Treatments
 
Full text article in PDF: